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Scenes
from the course Geology
and Environmental Science of Hawaii, Jan. 2000 |
Associate Professor of Chemistry 238 Ferguson
Science Center |
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Curriculum
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The effect of acid deposition on aquatic systems has been the subject of intensive research for many years. However, the vast majority of this research has focused on the impact of acid deposition on poorly buffered lakes in which the lake water pH has decreased and the aquatic life of the lake thus dramatically altered. I hypothesize that plant nutrients, specifically nitrates and phosphates, present in acid deposition enhance eutrophication in well buffered lakes in which the pH does not decrease significantly. Eutrophication is caused by extensive plant growth. Although phosphates do not contribute to acid rain they may be associated with particulate matter from similar pollution sources. Currently, pH and a low acid neutralizing capacity (ANC), also called alkalinity, are used as the primary indicators for acid deposition impact on surface water bodies. However, if the hypothesis stated above is correct, many buffered lakes within the mid-western and eastern U.S. may be affected by acid deposition through eutrophication, but without a significant decrease in pH. Hartwick College has owned the majority of the watershed contributing runoff to Pine Lake since the late 1960's. Therefore, there are few anthropogenic sources of nitrates and phosphates to Pine Lake. Nutrient concentrations in Pine Lake water as well as in wet and dry deposition to the Pine Lake watershed are being monitored in order to determine if background atmospheric inputs in this region contribute sufficient nutrients to promote eutrophication.
The ultimate fate of toxic metals in subsurface environments is largely controlled by their attraction, or sorption, to subsurface materials. How strongly the metals sorb to subsurface materials will determine the distance they will travel from their source as well as the ease (or difficulty) by which they may be desorbed from the subsurface materials during remediation. Sorption strength is, in part, controlled by the sorption mechanism. Selective extraction techniques may be used to determine the mechanism of sorption. Metals attracted to subsurface materials by electrostatic forces may be easily extracted by solutions of competing cations. This process is similar to recharging an ion exchange column used to soften tap water. Metals held to subsurface materials by chemical bonds are more difficult to extract. A complexant that binds more strongly to the metal than does the subsurface material may be required. Finally, metals may diffuse into the crystal structure of subsurface materials where they replace other cations in the crystal structure. Extraction of these metals may require dissolution of the crystal by acid or a reducing agent. A series of selective extractions are being used to determine the sorption mechanism of Ni, Pb, and Cu to subsurface materials. The mechanism of sorption will be correlated to the length of time the subsurface material has been contaminated by the metal. It is hypothesized that the longer the time available for sorption the more difficult it will be to desorb the metal from the subsurface material. This research has significant implications to both subsurface metal transport and remediation.
Complex
biological, geochemical, hydrological, and chemical processes control
subsurface contaminant transport. Many aspects of these processes have
been, and are currently being, studied mechanistically at the laboratory
scale. In order to describe the interrelationships between these
different processes under more realistic field scale heterogeneities, field
scale tests are required. I was part of a multi-disciplinary team of
scientists who designed and implemented integrated laboratory and field scale
adsorption, aquifer pumping, and infiltration tests. These tests helped quantitate the significance of preferential flow under both
saturated and unsaturated conditions, quantitate the
extent of adsorption equilibrium under field conditions, and evaluate the
applicability of laboratory measured parameter values in describing contaminant
transport in the field.
Colloids may sorb significant quantities of pollutants due to their large surface areas relative to their mass. The fate of colloids, and pollutants sorbed to colloids, is a function of their size distribution, morphology, and composition, as well as the chemistry and flow patterns of the water body. A series of fractionation steps and analytical procedures were developed to non-destructively characterize colloids in the Rhine River. This data was used with current coagulation-sedimentation models to evaluate the processes controlling the colloidal concentration and size distribution and to predict the fate of colloids and colloid-associated pollutants in the Rhine River.
Association of groundwater contaminants with mobile colloids may result in more rapid contaminant transport than predicted by current models. In order to more accurately estimate the risk to human health resulting from groundwater contamination, colloid-associated contaminant transport was considered. Laboratory column studies demonstrated that alterations in groundwater chemistry could result in the mobilization and subsequent transport of colloids. This work demonstrated that the effects of solution chemistry on colloid mobilization and transport must be considered in designing waste disposal and treatment processes because most contaminant inputs to groundwater can alter the solution chemistry.
Mercury concentrations in soil/sediment, water, and fish tissue were determined before, during, and after the construction of Richard B. Russell Reservoir, a lake on the Savannah River, in order to test the hypothesis that natural background levels of mercury in soil can be mobilized through microbial methylation into the waters of newly impounded reservoirs leading to elevated mercury concentrations in edible fish. Measured increases in the mercury concentration of fish tissue and changes in mercury speciation from primarily inorganic to primarily organic forms supported this hypothesis.
Mars
Hill College, 2008 - , Assistant Professor of
Chemistry. The responsibilities of this position include (1) teaching courses
such as general chemistry, descriptive inorganic chemistry, and analytical
chemistry, and (2) guiding undergraduate student research in chemistry.
Thomas
Jefferson Classical Academy, 2007 - 2008, Instructor. The responsibilities of
this position included (1) teaching chemistry and biology courses and (2)
organizing and setting up a teaching laboratory.
Hartwick
College, 2004 - 2007, Associate
Professor of Chemistry and Geology, and Chair of the Chemistry Department. The responsibilities of this
position include (1) teaching courses such as environmental chemistry,
chemistry for non science majors, general chemistry, environmental geology,
geochemistry, and geohydrology in both the chemistry
and geology departments, (2) guiding undergraduate student research in both
chemistry and geology, (3) administrative duties such as reviewing annual
faculty evaluations, submitting and administering the departmental budget, and
shepherding the development and implementation of a departmental assessment
plan.
Hartwick
College, 2001 - 2003, Associate Professor
of Chemistry and Geology, and Coordinator of the Environmental Science and
Policy Program. The responsibilities of this position include
(1) teaching courses such as environmental chemistry, chemistry for non science
majors, general chemistry, environmental geology, geochemistry, and geohydrology in both the chemistry and geology departments,
(2) guiding undergraduate student research in both chemistry and geology, (3)
encouraging students to enter the environmental field, providing them guidance
in career options, organizing and promoting student participation in
extracurricular environmental activities, and general administrative duties in
organizing the environmental science and policy program.
Hartwick College, 1996 - 2001, Assistant Professor of Chemistry and Geology, and Coordinator of the Environmental Science and Policy Program.
Clemson University, 1997 - , Affiliate Faculty, Environmental Engineering and Science. This position primarily entails supervising graduate research and serving on graduate student committees.
Clemson University, 1995-1996, Assistant Professor/Research Associate, Environmental Systems Engineering. This position entailed teaching a course in groundwater hydrology which covered such topics as saturated groundwater flow, natural groundwater chemistry, types and sources of contaminants, factors effecting contaminant transport, incorporation of contaminant transport in groundwater flow models, groundwater sampling, and groundwater contaminant remediation. This position also entailed actively pursuing research funding and supervision of graduate students.
The University of Idaho, 1995, Affiliate Faculty, Environmental Sciences. This position involved teaching a graduate course at the Idaho Falls campus in subsurface contaminant fate and transport which covered such topics as weathering reactions, natural groundwater chemistry, sources and types of contaminants, unsaturated and saturated fluid transport, factors affecting contaminant transport, and incorporation of contaminant transport in groundwater flow models. This position also entailed serving on graduate student committees.
Idaho National Engineering Laboratory, 1992-1996, Senior Scientist, Integrated Earth Sciences. This position entailed actively pursuing external funding. I was the principal investigator for two projects funded by DOE. I was responsible for setup and operation of a research laboratory at the INEL including purchasing equipment, and hiring, training, and oversight of laboratory personnel, as well as oversight of graduate students working under a subcontract with Clemson University.
The University of Geneva, 1990-1992, Post-doctoral Researcher, Dept. of Analytical Chemistry. This position entailed working within an interactive group of four scientists. Responsibilities included experiment design and execution, organization of sampling expeditions, use of numerous analytical techniques and instruments, data organization and interpretation, presentation of results at conferences, and writing publications and reports to funding agencies.
Clemson University, 1987-1988, Instructor, Environmental Systems Engineering. Duties included full teaching responsibility for a senior level undergraduate course designed to introduce civil engineering students to the varied topics covered in environmental engineering, including environmental chemistry, water and wastewater treatment, hazardous waste handling and disposal, surface and groundwater contaminant transport, and risk assessment.
Clemson University, 1983-1989, Teaching Assistant, Environmental Systems Engineering. Duties included preparation and demonstrations for laboratories, assigning and grading homework, and helping students to grasp the concepts presented in graduate level environmental chemistry and engineering courses.
Medical College of Georgia, 1981-1983, Laboratory Chemist, Department of Reproductive Endocrinology. Responsibilities included use of numerous analytical techniques and instruments, as well as data organization, interpretation, and presentation.
Education
Symposia
and Workshops Organized
Professional
Journals and Funding Agencies for Which I Have Reviewed
Chemistry
Environmental
Science and Engineering
Geology
General
Education
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Introduction to Physical
Science (Mars Hill College)
Bhalla, V.K., V.P. Rajan, and M.E. Newman. 1983. Alcohol Induced Luteinizing Hormone Receptor Deficiency at the Testicular Level. Alc. Clin. Ex. 7(2): 153-162.
Looney, B.B., M.E. Newman, and A.W. Elzerman. 1990. Colloid Facilitated Transport in Groundwater: Laboratory and Field Studies. Hazardous Materials Control 3(4): 47-49.
Newman, M.E., A.W. Elzerman, and B.B. Looney. 1993. Facilitated Transport of Selected Metals in Laboratory Soil Columns. J. Contam. Hydrol. 14(3): 233-246.
Perret, D., M.E. Newman, J.C. Negre, Y. Chen, and J. Buffle. 1993. Submicron Particles in the Rhine River -- I. Physico-Chemical Characterization. Water Res 28(1): 91-106.
Newman, M.E., M. Filella, D. Perret, J.C. Negre, Y. Chen, and J. Buffle. 1993. Submicron Particles in the Rhine River -- II. Comparison of Field Observations and Model Predictions. Water Res 28(1): 107-118.
Dunnivant, F.M., M.E. Newman, I. Porro, C. Bishop, J. Hubbell, J.R. Giles. 1997. Verifying the Integrity of Annular and Back-Filling Seals for Monitoring Wells. Groundwater 35(1): 140-148.
Filella, M., J. Zhang, M.E. Newman, and J. Buffle. 1997. Analytical Applications of Photon Correlation Spectroscopy for Size Distribution Measurements of Natural Submicron Colloidal Suspensions: Capabilities and Limitations . Colloids and Surfaces, A: Physiochemical and Engineering Aspects. 120: 27-46.
Dunnivant, F.M., C.W. Bishop, J.D. Burgess, J.R. Giles, B.D. Higgs, J.M. Hubbell, E. Neher, M.E. Newman, G.T. Norrell, M.C. Pfiefer, I. Porro, J.B. Sisson, R.C. Starr, and A.H. Wylie. 1998. Water and Radioactive Tracer Flow in a Heterogeneous Field-scale System. Groundwater 36(6): 949-958.
Dunnivant, F.M., M.J. Alfano, R. Brzenk, A. Moore, and M.E. Newman. 1999. A Comprehensive Stream Study Designed for an Undergraduate Non-majors Course in Earth Systems Science . J. of Geologic Education. 47: 158-164.
Dunnivant, F.M., A. Moore, M.J Alfano, R. Brzenk, P.T. Buckley, and M.E. Newman. 2000. Understanding the Greenhouse Effect: I s Global Warming Real? An Integrated Lab-Lecture Exercise for Non-Science Majors. J. of Chemical Education. 77(12): 1602-1603.
Porro, I., M.E. Newman, and F.M. Dunnivant. 2000. Strontium Distribution Coefficients Determined Under Various Saturation Levels in Basalt. Envrion. Sci. & Tech. 34(9): 1679-1686.
R.A. Fjeld, DeVol, T.A., R.W. Goff, M.D Blevins, S.M Ince, A.W Elzerman, and M.E. Newman. 2001. Column Test Analysis of Selected Actinides and Fission/ Activation Product Transport through Subsurface Basalt and Sedimentary Interbed Materials from the Snake River Plain . Nucl. Tech. 35: 92-108
Dunnivant F.M., D. Danowski, A. Timmons-Haroldson, M.E. Newman . 2002. Enviroland: A simple Computer Program for Quantitative Stream Assessment. The American Biology Teacher . 64(8): 589-595.
Dunnivant, F.M., D. Danowski, M.E. Newman, T. Spano, and F. Frye. 2002. Teaching Chemical Speciation to Environmental Chemists and Geochemists using Enviroland. J. of Geoscicence Education . 50(5).
Dunnivant, F.M., D. Danowski, and M.E. Newman. 2002. Teaching Pollutant Fate and Transport Concepts to Undergraduate Non-Science Majors, Environmental Scientists, and Hydrologists using Enviroland. J. of Geoscicence Education 50(5).
J.S. Powers, Kalicin, M., and M.E. Newman. 2004. Tree species do not influence local soil chemistry in a species-rich Costa Rica rain forest. J. of Tropical Ecology. 20:587-590.
Buffle, J., D. Perret,
M.E. Newman . 1992. The Use of Filtration and Ultrafiltration for Size Fractionation of Aquatic
Particles, Colloids and Macromolecules, in Characterization of Environmental Particles . J. Buffle and H.P. van Leeuwen,
Eds., Lewis Publishers Inc., Chelsea, MI.
Schurtenberger, P., M.E. Newman. 1993. Characterization of Biological and Environmental Particles Using Static and Dynamic Light Scattering, in Characterization of Environmental Particles: II . J. Buffle and H.P. van Leeuwen, Eds., Lewis Publishers Inc., Chelsea, MI.
M.E. Newman. 2005. The Chemistry of the Environment, in Chemistry and Chemical Reactivity, 6th Ed., J.C. Kotz and P.M. Treichel, Jr., Eds., Thompson Learning Inc., USA.
Abernathy, A.R., M.E. Newman , and W.D.
Nicholas. 1985. Mercury Mobilization from Soil and Its Uptake by Fish
Resulting from the Filling of Richard B. Russell Reservoir . Completion
Report to the U.S. Army Corps of Engineers, Environmental Lab., Waterways
Experiment Station, Vicksburg, MS.
Abernathy, A.R., M.E. Newman, and W.D. Nicholas. 1985. Mercury Mobilization and Biomagnification Resulting from the Filling of a Piedmont Reservoir. Completion Report to Water Resources Research Institute, Clemson University, Clemson, SC. G-932-07.
Buffle, J., Y. Chen, J.C. Negre, M.E. Newman, and D. Perret. 1992. Characterization of Colloidal Particles in the Rhine River and Their Role in the Elimination of Micropollutants. Completion Report to Sandoz Funds for the Rhine River, Sandoz Technology Ltd., Basle, Switzerland.
Newman, M.E. 1994. Integrated Large-Scale Aquifer Pumping and Infiltration Tests - Water Sampling and Analysis Test Plan . Idaho National Engineering Laboratory, Idaho Falls, ID, EGG-ER-11367.
Newman, M.E., F.M. Dunnivant. 1995. Results from the Large-Scale Aquifer Pumping and Infiltration Test: Transport of Tracers Through Fractured Media. Idaho National Engineering Laboratory, Idaho Falls, ID. INEL-95/146, ER-WAG7-77.
Newman, M.E., I. Porro, R. Scott, F.M. Dunnivant, R.W. Goff, M.D. Blevins, S. M. Ince, J.D. Leyba, T.A. DeVol, A.W. Elzerman, R.A. Fjeld. 1995. Evaluation of the Mobility of Am, Cs, Co, Pu, Sr, and U through INEL Basalt and Interbed Materials: Summary Report of the INEL/Clemson University Laboratory Studies. Idaho National Engineering Laboratory. Idaho Falls, ID, INEL-95/282, ER-WAG7-82.
Dunnivant, F.M., and M.E. Newman. 1995. Preliminary Modeling of Breakthrough Curves from the Large-Scale Aquifer Pumping and Infiltration Test. Idaho National Engineering Laboratory, Idaho Falls, ID, INEL-95/288, ER-WAG7-84.
Lacy, C., L. Malloy, S. Carbone, M.E. Newman, M. Allen. 2004. Women & Science Roundtable – Gotsch Symposium on Women and Work. Phoebe: Gender & Cultural Critiques. 16(2): 49-60.
Newman, M.E., and A.R. Abernathy. Mercury Accumulation by Fish in Richard B. Russell Reservoir . South Carolina Academy of Sciences 59th Annual Meeting, Clemson University, April, 1986.
Newman, M.E., A.R. Abernathy, and A.W. Elzerman. Mercury Mobilization Resulting from the Filling of Richard B. Russell Reservoir . Division of Environmental Chemistry, American Chemical Society, Anaheim, CA, Sept., 1986.
Newman, M.E., and A.W. Elzerman. Enhanced Mobility of Waste Derived Metals in Column Studies of Groundwater Transport . Division of Environmental Chemistry, American Chemical Society, New Orleans, LA, Sept., 1987.
Newman, M.E., A.W. Elzerman, and B.B. Looney. Facilitated Transport of Selected Metals in Laboratory Soil Columns . Division of Environmental Chemistry, American Chemical Society, Miami, FL, Sept., 1989.
Newman, M.E., and A.W. Elzerman. Facilitated Transport of Selected Metals in Soil Packed Laboratory Columns . 2nd Soil Residue Analysis Workshop. International Association of Environmental Analytical Chemistry. Ecole Polytechnique Federale de Lausanne, Switzerland, March, 1991.
Newman, M.E., F.M. Dunnivant, and J.B. Sisson. Transport of Radionuclides through Fractured Media during the Large-Scale Aquifer Pumping and Infiltration Test . Poster, American Geophysical Union, Baltimore, MD, May, 1995.
Moore, A. Brzenk, R., Buckley, P., Hamilton, D. Nagel, W., Newman, M.E., and Young, S., Improving Science Literacy in General Education: An Interdisciplinary Course Sequence In Earth Systems Science, Second International Conference on Geoscience Education, Hilor, Hawaii, July 28-August 1, 1997.
Newman, M.E., Growing Pains: Observations on Starting a New Environmental Chemistry Program at Undergraduate Institutions, 221st American Chemical Society National Meeting, San Diego, CA, April 2001.
Newman, M.E., Relationships between Suspended Solids, Total Solids, Conductivity, Turbidity, Ionic Strength, and Activity Illustrated in a Laboratory Exercise, 221 st American Chemical Society National Meeting, San Diego, CA, April 2001.
Newman, M.E., Teaching Environmental Science Outdoors, 75th New York State Geological Association Annual Meeting, Oneonta, NY, October 2003.
R.M. El-Farhan, A.W. Elzerman, and M.E. Newman . Contaminant Plume Modification Effects on Heavy Metal Sorption and Release from SRS Soil, Emerging Technologies in Hazardous Waste Management VIII, The Industrial & Engineering Chemistry Division of the American Chemical Society, Birmingham, AL, Sept., 1996.
M.H. Kalicin, and M.E. Newman. The Significance of Atmospheric Inputs to the Nutrient Load and Budget of Pine Lake , Poster, American Geophysical Union, Boston, MA, May, 1998.
M.J. Alfoano, R. Brzenk, P. Buckley, F. Dunnivant, D. Hamilton, A. Moore, M.E. Newman, and S. Young, An Integrated, Interdisciplinary Course Sequence in Earth Systems Science , American Geophysical Union, Boston, MA, May 1998.
F. Frye, F. Dunnivant, and M.E. Newman, Effects of EDTA on Copper Transport in a Ground Water System, The NY Regional Meeting of the American Chemical Society, Skidmore College, April 26, 1998.
M.H. Kalicin, and M.E. Newman, The Effect of Tree Species on Soil Chemistry and Nutrients in a Tropical Wet-Forest in Costa Rica, Poster, 217th American Chemical Society National Meeting, Anaheim, California, March 21-25, 1999.
M.H. Kalicin, and M.E. Newman, The Significance of Atmospheric Inputs to the Nutrient Load and Budget of Pine Lake , Poster, Northeast Regional Meeting (NERM) of the American Chemical Society, Clarkson University, Potsdam, NY, June 22-25, 1999.
D.A. Danowski, D.M. Dunnivant, and M.E. Newman, An Interactive Computer Tool for Teaching Hydrology, Geological Society of America, Denver, CO, October, 1999.
T.A. Spano and M.E. Newman, Nutrient Budget for a Well-Buffered Lake in Upstate New York, 219th American Chemical Society National Meeting, Poster, San Francisco, CA, March 26-30, 2000.
O.V. Barker and M.E. Newman, Selective Extraction of Metals from Contaminated Soils Using Organic Complexants , 219 th American Chemical Society National Meeting, San Francisco, CA, March 26-30, 2000.
N.A. Steele and M.E. Newman, The Effects of Acid Rain on a Well Buffered Lake, Council on Undergraduate Research, Posters on the Hill, Washington D.C., March 2001.